A new family of high nuclearity CoII/DyIII coordination clusters possessing robust and unseen topologies
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منابع مشابه
A new family of high nuclearity Co(II)/Dy(III) coordination clusters possessing robust and unseen topologies.
Mixing Co(NO3)2·6H2O/Dy(NO3)3·6H2O/(E)-4-(2-hydroxy-3-methoxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one (HL)/pivalic acid/Et3N in various solvents results in the synthesis of seven compounds formulated as [CoII2DyIII2(μ3-MeO)2(L)2(piv)4(NO3)2] (3), [CoIIDyIII3(μ3-MeO)2(μ2-MeO)2(L)2(piv)2(NO3)3]·2(CH3OH) (4·2CH3OH), 2[CoII4DyIII4(μ2-O)2(μ3-OH)4(L)4(piv)8][CoII2DyIII5(μ3-OH)...
متن کاملA new family of high nuclearity CoII / DyIII coordination clusters possessing robust and unseen topologies † Benjamin Berko ff , a Kieran Gri ffi ths , a Alaa Abdul - Sada , a Graham
Mixing Co(NO3)2·6H2O/Dy(NO3)3·6H2O/(E)-4-(2-hydroxy-3-methoxybenzylideneamino)-2,3-dimethyl-1phenyl-1,2-dihydropyrazol-5-one (HL)/pivalic acid/Et3N in various solvents results in the synthesis of seven compounds formulated as [Co 2Dy III 2 (μ3-MeO)2(L)2(piv)4(NO3)2] (3), [Co Dy 3 (μ3-MeO)2(μ2MeO)2(L)2(piv)2(NO3)3]·2(CH3OH) (4·2CH3OH), 2[Co II 4Dy III 4 (μ2-O)2(μ3-OH)4(L)4(piv)8][Co II 2Dy III 5...
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A novel 2-D coordination polymer constructed from high nuclearity nanosized Ho48 clusters was synthesised and structurally characterized using single-crystal X-ray analysis. The Ho48 cluster core with a charming waist drum-like structure was templated by CO3(2-) ions, and bridged by Ho-N bonds to get a 2-D coordination polymer.
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2015
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c5dt01813g